SYPMAT UC3M

SYPMAT: a multidisciplinary research group (SYnthesis and Processing of MATerials)

The Universidad Carlos III de Madrid is one of the six Public Universities that there are in Madrid. It is a really young University, it was created in 1988.
There are three campuses (Getafe and Leganés in the south of Madrid, about 15 km from downtown) and Colmenarejo in the West part of Madrid and far away from the city about 45 km).
In Leganés, where we are, is located the Engineering School.
Here some pictures of Leganes Campus. And here appear some figures of our University:


21.047

Students at UC3M
20% of them are foreign.

2.020

Teachers & researchers.
Average age is 42 years old.

The University is the best young university in Spain, according to the latest QS Top 50 Under 50 ranking. Currently is located in the 22 position.


Data of involved researchers:

Prof.Jean-Yves Sanchez (Chair of Excellence UC3M).
Coordinator of the FETOPEN project VIDICAT: 1/03/2019 to 1/03/2023.
Contact: +34 916249447 (jeasanch@ing.uc3m.es)

Research Focus:
Electrochemical Storage and Conversion of Energy i.e. Batteries (Li-ion & post) and P.E.Fuel Cells. Invention of Molecular and Macromolecular materials i.e. Salts, Host Polymers, Ionomers, Redox Organic Electrodes. Synthesis and characterization of electrolytes and electrodes. Safety: thermomechanical reinforcement through a nanocomposite approach based on safe cellulose nanofibers. Green processing: removing VOC by casting electrolyte from water solutions and/or extruding.

Related Publications:
A non-conventional fluorinated separator in high-voltage graphite/LiNi0.4Mn1.6O4 cells”. C.Arbizzani, F.Colò, F.De Giorgio, M.Guidotti, M.Mastragostino, F.Alloin, M.Bolloli,Y.Molméret, J-Y.Sanchez., J.Power Sources, 246 (2014) 299-304.
“Highly Phase Separated Aromatic Ionomers Bearing Perfluorosulfonic Acids by Bottom-up Synthesis: Effect of Cation on Membrane Morphology and Functional Properties, O.Danyliv, C.Iojoiu, S.Lyonnard, N.Sergent, E.Planes, J-Y.Sanchez, MACROMOLECULES, 49-11 (2016) 4164-4177.“Lithium salts based on a series of new anilinyl-perfluorosulfonamide salts and their polymer electrolytes”, A.Thiam, C. Iojoiu, J-C. Leprêtre, J-Y. Sanchez, J.Power Sources, 364(2017)138-147.


Prof. Alejandro VÁREZ (Full Professor in Materials Science).
Head of Synthesis and Processing of Materials Research Group.
Contact: +34 91 6249484 (alvar@ing.uc3m.es)

Research Focus:
Energy materials, Synthesis and characterization of ion conductors (inorganic and polymers), Structural characterization (neutron and X-ray diffraction),  impedance spectroscopy, Processing of ceramic powders: Powder Injection Moulding, Powder Extrusion Moulding, Tape Casting and 3-D printing.

Related Publications:
“Unravelling the complex nanostructure of La0.5−xLi0.5−xSr2xTiO3 Li ionic conductors”. E. Garcia-Gonzalez, E. Urones,  A. Varez, J. Sanz. Dalton Transactions ,45, 7148-7157, (2016).
“Sodium polymer electrolytes composed of sulfonated polysulfone and macromolecular/molecular solvents for Na-batteries” , C.S. Martinez-Cisneros, C. Antonelli, B. Levenfeld, A. Varez, J.Y. Sanchez, Electrochimica Acta,  245, (2017), 807-813.


Prof. Belén LEVENFELD (Full Professor in Materials Science)
Head of Synthesis and Processing of Materials Research Group
Contact: +34 91 6249484 (alvar@ing.uc3m.es)

Research Focus:
Processing of metal and ceramic powders: Powder Injection Moulding (PIM), Powder Extrusion Moulding (PEM), Tape Casting and 3-D printing. Design and development of polymeric binder systems for the shaping of ceramic and metallic materials through these technologies. We are currently applying PIM, PEM and Tape Casting technologies to obtain electrodes for Li batteries.
Energy materials. Synthesis and characterization of polymeric membranes with high protonic and anionic conductivity for fuel cell applications..
Synthesis and characterization of polymer electrolyte for Li and Na batteries.

Related Publications:
“Additives-free Li4Ti5012 thick electrodes for Li-ion batteries with high electrochemical performances” M.E. Sotomayor, C. de la Torre-Gamarra, W. Bucheli, J.M. Amarilla, A. Varez, B. Levenfeld, J.Y. Sanchez, Journal of Materials Chemistry A, 6, (2018), 5952- 5961
“Synthesis and characterization of benzimidazolium-functionalized polysulfones as anion-exchange membranes” M.T. Pérez Prior, A. Várez, B. Levenfeld. Journal of Polymer Science Part A-Polymer Chemistry, 53, 20, 2363-2373 (2015).


Dr. Cynthia MARTINEZ-CISNEROS (PhD Post-Doc)
Responsible for Post-lithium Batteries (PLIB)
Contact: +34 91 6248374 (cymartin@ing.uc3m.es)

Research Focus:
Materials for energy applications, synthesis and characterization of ion conductors (inorganic and polymers) with the electrochemistry of sodium and calcium, towards rechargeable post-lithium ion batteries.

Related Publications:
“Development of sodium-conducting polymer electrolytes: comparison between film-casting and films obtained via green processes”, C. Martinez-Cisneros, B. Levenfeld, A. Varez, J-Y. Sanchez, Electrochimica Acta, 192, (2016), 456-466.
“Evaluation of polyolefin-based macroporous separators for high temperature Li-ion batteries” C. Martinez-Cisneros, C. Antonelli, B. Levenfeld, A. Varez, J-Y. Sanchez, Electrochimica Acta, 216, (2016), 68-78.


Dr. María Teresa PÉREZ-PRIOR (PhD Post-Doc)
Responsible for Anion-Exchange Membrane Fuel Cells (AEMFC)
Contact: +34 91 6248863 (maperezp@ing.uc3m.es)

Research Focus:
Materials for energy applications, synthesis and characterization of Anion-Exchange Membranes (AEMs) for low temperature fuel cells.

Related Publications:
“DABCO‐functionalized polysulfones as anion‐exchange membranes for fuel cell applications: Effect of crosslinking” Pérez Prior, M. T.; Ureña, N.; Tannenberg, M. del Río, C.; Levenfeld, B. J. Polym. Sci. Part B: Polym. Phys., 55, 1326-1336 (2017)
“Synthesis and characterization of benzimidazolium-functionalized polysulfones as anion-exchange membranes” M.T. Pérez Prior, A. Várez, B. Levenfeld. J. Polym. Sci. Part A: Polym. Chem., 53, 2363-2373 (2015)


Carmen de la Torre Gamarra (PhD)
PhD of Synthesis and Processing of Materials Research Group
Contact: +34 91 6248863 (catorreg@ing.uc3m.es)

Research Focus:
Materials for energy applications: solid-state electrolytes and ceramic electrodes for rechargeable batteries. Specialized in:
· Synthesis of solid ionic conductors.
· Processing of ceramic powders by Powder Extrusion Moulding (PEM) and Tape Casting for Li-ion batteries electrodes manufacturing.
· Structural and microstructural characterization by X-Ray Diffraction and Electronic Microscopy (SEM, TEM).
· Electrochemical characterization: Electrochemical Impedance Spectroscopy and Galvanostatic cycling.

Related Publications:
“Na3Si2Y0.16Zr1.84PO12-ionic liquid hybrid electrolytes: An approach for realizing solid-state sodium-ion batteries?” C. de la Torre-Gamarra, G.B. Appetecchi, U. Ulissi, A. Varzi, A. Varez, S. Passerini, J. Power Sources. 383 (2017) 157–163.
“Additives-free Li4Ti5012 thick electrodes for Li-ion batteries with high electrochemical performances” M.E. Sotomayor, C. de la Torre-Gamarra, W. Bucheli, J.M. Amarilla, A. Varez, B. Levenfeld, J.Y. Sanchez, Journal of Materials Chemistry A, 6, (2018), 5952- 5961.


Raúl San Román Gallego Casilda (PhD)
Contact: rsanroma@ing.uc3m.es

Academic training:
Master in Organic Chemistry, 2019
Universidad Autónoma de Madrid, Madrid (Spain)
Graduate in Chemistry ,2017
Universidad Autónoma de Madrid, Madrid (Spain).

Research Focus:
Ni-catalyzed reactions of:
• Borilative cyclization of insaturated compounds.
• Cyclization and Negishi cross-coupling reaction with redox active esters.


Bidhan Pandit (PhD Post-Doc)
Contact: physics.bidhan@gmail.com

Research Focus:
Synthesis of nanostructures for next-generation energy storage applications (lithium/sodium ion batteries and supercapacitors) and fabrication of flexible energy storage devices to investigate electrochemical behaviors.
Research approach includes both experimental and modeling approaches to polymeric, carbon, metallic, mineral oxide, hybrid or composite materials.
Special effort is dedicated to the structuring, at different scales, of the materials, in coherence with their implementation

Related Publications:
B. Pandit, D.P. Dubal, P. Gómez-Romero, B.B. Kale, B.R. Sankapal,” V2O5 encapsulated MWCNTs in 2D surface architecture: Complete solid-state bendable highly stabilized energy efficient supercapacitor device”, Scientific Reports 7 (2017) 43430.
B. Pandit, S.S. Karade, B.R. Sankapal, Hexagonal VS2 Anchored MWCNTs: “First Approach to Design Flexible Solid-State Symmetric Supercapacitor Device”, ACS Applied Materials & Interfaces 9 (2017) 44880-44891
B. Pandit, C. Jadhav, P. Chavan, H. Tarkas, J. Sali, R. Gupta, B. Sankapal, “2D Hexagonal SnSe nanosheets as binder-free electrode material for high-performance supercapacitors”, IEEE Transactions on Power Electronics, (2020)


Jose Francisco Vivo-Vilches (PhD Post-Doc)
Contact: jvivo@ing.uc3m.es

Research Focus:
• Gas separation and air purification by adsorption onto different carbon materials
• Development of materials based on lignin and other molecules obtained from bioresources and their use as electrodes for Vanadium Redox Flow Batteries (VRFBs)
• Redox Targeting Redox Flow Batteries: test a semisolid RFB based on the addition of a solid booster to the electrolyte tanks reacting with the soluble species (mediator) in order to increase the volumetric energy density of the battery

Related Publications:
“Lignin-Based Carbon Nanofibers as Electrodes for Vanadium Redox Couple Electrochemistry”. J.F. Vivo-Vilches, A. Celzard, V. Fierro, I. Devin-Ziegler, N. Brosse, A. Dufour, M. Etienne. Nanomaterials, 9 – 1, 106, (2019).
“Layer-by-Layer modification of graphite felt with MWCNT for vanadium redox flow battery”. M. Etienne, J.F. Vivo-Vilches, I. Vakulko, C. Genois, L. Liu, M. Perdicakis, R. Hempelmann, A. Walcarius. Electrochimica Acta, 313, 131 – 140, (2019).
“LiFePO4-ferri/ferrocyanide redox targeting aqueous posolyte: Set-up, efficiency and kinetics”. J.F. Vivo-Vilches, A. Nadeina, N. Rahbani, V. Seznec, D. Larcher, E. Baudrin. Journal of Power Sources, 488, 229387, (2021).


RESEARCH AREAS OF SYPMAT

We are focused on Synthesis, Characterization and Processing of Materials for Energy.
Two main areas are distinguished: Electrical Storage and Electricity Production.
Regarding to Energy Storages the main lines are Li-batteries and Post-Li batteries. And we have also worked in Redox-Flow batteries and Phase Change Materials.
In relation to Electricity Production our interest is focused on Fuel Cells: Mainly Polymer exchange membranes and Solid Oxide Fuel Cells.
For more than 15 years, and associated with the powder injection molding research line, we have collaborated with two companies related to magnetic ferrites, a manufacturer of ferrites and another manufacturer of electronic components.
Recently we are also involved in Additive Manufacturing, in particular in 3D printing using fused filament fabrication.

Technical Capabilities:

We have a full equipped synthesis Lab, with some chemical analytical capabilities.
• Ceramic Method (RT-1800ºC), sol-gel, spray pyrolysis, hydrothermal,
• Elemental Chemical Analysis (C,N, S, O), Atomic Absortion, XRF, EDS.
• Particle size, specific Surface, density, etc.
• Dry boxes.

Also we have a Powder Injection/Extrusion Moulding Laboratory and 3-D lab. It is the only one, full equipped in Spain and one of the few in Europe.
• Injection Machine (30Tm), extruder, rheometers (capillary,…).
• Sintering and debinding furnaces 100-1800ºC (different atmosphere (even pure H2)).
• 3-D Printing, Tape casting.

We have also a conventional Structural and Microstructural laboratory with XRD (RT-1500ºC), SEM, FEG-SEM, TEM. AFM, OM.

Also we have a nice and full equipped thermal characterization laboratory
• DSC (RT-600 ºC), TGA (RT 1500ºC), DTA (RT-1500ºC) DMTA.
Mechanical Characterization lab
• Hardness, microhardness, Tensile Strength, Tribometers,…
And finally an electrical Characterization laboratory.
• Impedance Analyzers with Electrochemical interface (10 μHz to 32 MHz) (RT-1000ºC), (30-95%HR).

Mention in the Media: